Download Carbohydrate Chemistry: v. 10 by J.S. Brimacombe PDF


By J.S. Brimacombe

ISBN-10: 0851860923

ISBN-13: 9780851860923

Carbohydrate Chemistry offers evaluate insurance of all guides proper to the chemistry of monosaccharides and oligosaccharides in a given 12 months. the volume of analysis during this box showing within the natural chemical literature is expanding as a result stronger significance of the topic, specially in parts of medicinal chemistry and biology. In no a part of the sector is that this extra obvious than within the synthesis of oligosaccharides required through scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well verified, for instance, through the coaching of particular carbohydrate- established antigens, in particular cancer-specific oligosaccharides and glycoconjugates. insurance of themes similar to nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot examine of relevance to organic and medicinal chemistry. every one quantity of the sequence brings jointly references to all released paintings in given components of the topic and serves as a complete database for the lively examine chemist. professional Periodical stories offer systematic and unique overview insurance in significant parts of chemical learn. Compiled through groups of major specialists within the suitable topic parts, the sequence creates a special provider for the lively learn chemist, with commonplace, in-depth money owed of development specifically fields of chemistry. topic insurance inside of assorted volumes of a given identify is identical and e-book is on an annual or biennial foundation.

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40%) and 6-0-benzoylcellobiose (59%) ;20s similar results have previously been observed with the corresponding @-maltoseand p-lactose heptabenzoates, signifying that a benzoyl group at 0 - 3 is required for the migration reaction that leads to formation of nitrogen-containing disaccharide derivatives. 207a In a reinvestigation of the conversion of /%maltose octa-acetate into 1,2’,3,3’,4’,6,6’hepta-0-acetyl-p-maltose, via the corresponding 2-trichloroacetyl @-chloride derivative, the intermediates have been isolated in crystalline form and fully characterized.

Gigg, and A. A. E. S. Perkin I, 1976, 1395. ls2 Other 1,6-anhydro-sugars are referred to in Chapters 6 , 7, 11, and 23. 181 lSa R. Chaby and P. , 1976, 49,489. K. Takeo, K. Mine, and T . , 1976,48, 197. lS3 4,6-Dichloro-4,6-dideoxy-~-gaIactose reacted with cyclohexanone ethylene acetal in the presence of an acid catalyst to give the acyclic derivative (48), which was converted into the corresponding 5 - u l 0 s e . ~ Treatment ~~ with base converted (48) into the 5,6-anhydro-derivative, which was hydrolysed to give the L-idose diacetal(49), presumably by way of a 4,5-anhydro-~-glucosederivative.

J. , 1976, 48, 65. H. G. Garg and R. W. , 1976, 49, 482. S. C. Chhabra, S. R. Gupta, C. S. Sharma, and N. D. Sharma, Indian J. , 1976, 14B, 384 (Chem. , 1976, 85, 193 025y). L. Farkas and J. Strelisky, in ‘Topics in Flavonoid Chemistry and Biochemistry’, Proceedings of the 4th Hungarian Bioflavonoid Symposium, 1973 (Pub. 1975), p. 149 (Chem. A s . , 1976, 85, 63 2942). M. Barczaibeke and C. Szantay, Acta Chim. Acad. Sci. , 1974, 80, 111 (Chem. , 1976,84,90 5002). C. Hansson and E. Rosengren, Actn Chem.

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